Controlling the Stereochemistry and Regularity of Butanethiol Self-Assembled Monolayers on Au(111).

The rich stereochemistry of the self-assembled monolayers (SAMs) of four butanethiols on Au(111) is described, the SAMs containing up to 12 individual C, S, or Au chiral centers per surface unit cell. This is facilitated by synthesis of enantiomerically pure 2-butanethiol (the smallest unsubstituted...

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Publicado en:	Journal of the American Chemical Society Vol. 136; no. 49; pp. 17087 - 17095
Autores principales:	Jiawei Yan, Runhai Ouyang, Jensen, Palle S., Ascic, Erhad, Tanner, David, Bingwei Mao, Jingdong Zhang, Chunguang Tang, Hush, Noel S., Ulstrup, Jens, Reimers, Jeffrey R.
Formato:	Artículo
Publicado:	American Chemical Society 12/10/2014
Materias:	Stereochemistry Molecular self-assembly Monomolecular films Chiral centers Alkanethiols Scanning tunneling microscopy Density functional theory Molecular dynamics
Acceso en línea:	Ver este registro en EBSCOhost