Evidence of σ- and π-Dimerization in a Series of Phenalenyls.

Phenalenyl and a wide variety of its derivatives form stable radicals, which often associate in various aggregates with interesting properties that include magnetism and high electrical conductivity. The two main modes of aggregation involve π-stacking pancake multicenter bond formation and σ-bond f...

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Publicado en:	Journal of the American Chemical Society Vol. 136; no. 52; pp. 18009 - 18023
Autores principales:	Zhongyu Mou, Kazuyuki Uchida, Takashi Kubo, Miklos Kertesz
Formato:	Artículo
Publicado:	American Chemical Society 12/31/2014
Materias:	Dimerization Phenalenyl radicals Stacking interactions Bond formation mechanism Density functional theory Potential energy surfaces Single crystals X-ray diffraction
Acceso en línea:	Ver este registro en EBSCOhost