Synthesis and Characterization of Coinage Metal Aluminum Sulfur Species.
The synthesis of heterobimetallic cluster with the Al--S--M (M = Cu and Ag) structural unit has been realized for the first time by the reaction of aluminum-dithiol LAl(SH) (L = HC[C(Me)N(Ar)], Ar = 2,6-iPrCH) with (MesCu) and (MesAg) (Mes = 2,4,6-MeCH), respectively. The isolated clusters exhibit c...
| Publicado en: | Journal of the American Chemical Society Vol. 137; no. 1; pp. 162 - 165 |
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| Autores principales: | , , , |
| Formato: | Artículo |
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American Chemical Society
1/14/2015
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| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=101328144&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 101328144 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 1/14/2015 vid: 137 iid: 1 pid: 997 pub: American Chemical Society artinfo: ui: 101328144 10.1021/ja511722a ppf: 162 ppct: 3 formats: tig: atl: Synthesis and Characterization of Coinage Metal Aluminum Sulfur Species. aug: au: Bin Li Jiancheng Li Roesky, Herbert W. Hongping Zhu affil: State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China Institut für Anorganische Chemie, Georg-August-Universität, Tammannstraβe 4, 37077 Göttingen, Germany su: Heterobimetallic complexes Metal complexes X-ray diffraction X-ray diffractometers Electromagnetic wave diffraction sug: subj: Heterobimetallic complexes Metal complexes X-ray diffraction X-ray diffractometers Electromagnetic wave diffraction ab: The synthesis of heterobimetallic cluster with the Al--S--M (M = Cu and Ag) structural unit has been realized for the first time by the reaction of aluminum-dithiol LAl(SH) (L = HC[C(Me)N(Ar)], Ar = 2,6-iPrCH) with (MesCu) and (MesAg) (Mes = 2,4,6-MeCH), respectively. The isolated clusters exhibit core structures of AlCuS and AlAgS, respectively. During the formation of the [LAl(SAg)], a side product of LAlS is formed. However, the reaction of LAl(SH) with excess of sulfur and (MesAg) resulted in the formation of LAlS as the only product soluble in organic solvents. Both of them represent rare examples of aluminum polysulfides. All compounds were characterized by spectroscopic methods and single crystal X-ray diffraction studies. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2015 holdings: @attributes: islocal: N |
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