Covalency in Lanthanides. An X-ray Absorption Spectroscopy and Density Functional Theory Study of LnCl (x = 3, 2).

Covalency in Ln-Cl bonds of O-LnCl (x = 3 for Ln = Ce, Nd, Sm, Eu, Gd; x = 2 for Ln = Ce) anions has been investigated, primarily using Cl K-edge X-ray absorption spectroscopy (XAS) and time-dependent density functional theory (TDDFT); however, Ce L-edge and M-edge XAS were also used to characterize...

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Publicado en:	Journal of the American Chemical Society Vol. 137; no. 7; pp. 2506 - 2524
Autores principales:	Löble, Matthias W., Keith, Jason M., Altman, Alison B., Stieber, S. Chantal E., Batista, Enrique R., Boland, Kevin S., Conradson, Steven D., Clark, David L., Pacheco, Juan Lezama, Kozimor, Stosh A., Martin, Richard L., Minasian, Stefan G., Olson, Angela C., Scott, Brian L., Shuh, David K., Tyliszczak, Tolek, Wilkerson, Marianne P., Zehnder, Ralph A.
Formato:	Artículo
Publicado:	American Chemical Society 2/25/2015
Materias:	Rare earth metals Desorption Oxidation states Fluid dynamics Radiation absorption
Acceso en línea:	Ver este registro en EBSCOhost