A new rosane-type diterpenoid from Stachys parviflora and its density functional theory studies.

A new rosane-type diterpenoid (1) has been isolated from the chloroform fraction of Stachys parviflora. Structure of 1 was proposed based on 1D and 2D NMR techniques including correlation spectroscopy, heteronuclear multiple quantum coherence, heteronuclear multiple bond correlation and nuclear Over...

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Publicado en:Natural Product Research Vol. 29; no. 9; pp. 813 - 820
Autores principales: Farooq, Umar, Ayub, Khurshid, Hashmi, Muhammad Ali, Sarwar, Rizwana, Khan, Afsar, Ali, Mumtaz, Ahmad, Manzoor, Khan, Ajmal
Formato: Journal Article
Publicado: Taylor & Francis Ltd May2015
Acceso en línea:Ver este registro en EBSCOhost
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        atl: A new rosane-type diterpenoid from Stachys parviflora and its density functional theory studies.
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        au:
          Farooq, Umar
          Ayub, Khurshid
          Hashmi, Muhammad Ali
          Sarwar, Rizwana
          Khan, Afsar
          Ali, Mumtaz
          Ahmad, Manzoor
          Khan, Ajmal
        affil: Department of Chemistry, COMSATS Institute of Information Technology, Abbottabad22060, Pakistan
      sug:
      ab: A new rosane-type diterpenoid (1) has been isolated from the chloroform fraction of Stachys parviflora. Structure of 1 was proposed based on 1D and 2D NMR techniques including correlation spectroscopy, heteronuclear multiple quantum coherence, heteronuclear multiple bond correlation and nuclear Overhauser effect spectroscopy. A theoretical model for the electronic and spectroscopic properties of compound 1 is also developed. The geometries and electronic properties were modelled at B3LYP/6-31G* and the theoretical scaled spectroscopic data correlate nicely with the experimental data.
      pubtype: Academic Journal
      doctype: Journal Article
      ougenre: Article
    language: English
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