The Homogeneous Reduction of CO by [Ni(cyclam)]: Increased Catalytic Rates with the Addition of a CO Scavenger.

The homogeneous electrochemical reduction of CO by the molecular catalyst [Ni(cyclam)] is studied by electrochemistry and infrared spectroelectrochemistry. The electrochemical kinetics are probed by varying CO substrate and proton concentrations. Products of CO reduction are observed in infrared spe...

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Publicado en:	Journal of the American Chemical Society Vol. 137; no. 10; pp. 3565 - 3574
Autores principales:	Froehlich, Jesse D., Kubiak, Clifford P.
Formato:	Artículo
Publicado:	American Chemical Society 3/18/2015
Materias:	Chemical reduction Catalysts Electrochemistry Chemical species Bicarbonate ions Macrocyclic compounds Density functional theory
Acceso en línea:	Ver este registro en EBSCOhost