Electronic and Spectroscopic Properties of Avobenzone Derivatives Attached to Mo Quadruple Bonds: Suppression of the Photochemical Enol-to-Keto Transformation.

From the reactions between Mo(TPB), where TPB is 2,4,6-triisopropylbenzoate, and 2 equiv of the acids 4-formylbenzoic acid, HBzald; 4-(3-oxo-3-phenylpropanoyl)benzoic acid, HAvo; and 4-(2,2-difluoro-6-phenyl-2H-1λ³,2λ-dioxaborinin-4-yl)benzoic acid, HAvoBF, the compounds Mo(TPB)(Bzald), I; Mo(TPB)(A...

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Publicado en:	Journal of the American Chemical Society Vol. 137; no. 15; pp. 5155 - 5163
Autores principales:	Chisholm, Malcolm H., Durr, Christopher B., Gustafson, Terry L., Render, William T., Spilker, Thomas F., Young, Philip J.
Formato:	Artículo
Publicado:	American Chemical Society 4/22/2015
Materias:	Molecular structure of ligands Electronic structure Emission spectroscopy Density functional theory Time-dependent density functional theory Benzoic acid
Acceso en línea:	Ver este registro en EBSCOhost