Dual Element Intercalation into 2D Layered BiSe Nanoribbons.
We demonstrate the intercalation of multiple zero-valent atomic species into two-dimensional (2D) layered BiSe nanoribbons. Intercalation is performed chemically through a stepwise combination of disproportionation redox reactions, hydrazine reduction, or carbonyl decomposition. Traditional intercal...
| Publicado en: | Journal of the American Chemical Society Vol. 137; no. 16; pp. 5431 - 5438 |
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| Autores principales: | , , , |
| Formato: | Artículo |
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American Chemical Society
4/29/2015
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| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=102674895&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 102674895 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 4/29/2015 vid: 137 iid: 16 pid: 997 pub: American Chemical Society artinfo: ui: 102674895 10.1021/jacs.5b00666 ppf: 5431 ppct: 7 formats: tig: atl: Dual Element Intercalation into 2D Layered BiSe Nanoribbons. aug: au: Chen, Karen P. Chung, Frank R. Mengjing Wang Koski, Kristie J. affil: Department of Chemistry, Brown University, 324 Brook St. Box H, Providence Rhode Island 02912, United States su: Nanoribbons Nanobelts Chemical reactions Carbonyl compounds Atoms sug: subj: Nanoribbons Nanobelts Chemical reactions Carbonyl compounds Atoms ab: We demonstrate the intercalation of multiple zero-valent atomic species into two-dimensional (2D) layered BiSe nanoribbons. Intercalation is performed chemically through a stepwise combination of disproportionation redox reactions, hydrazine reduction, or carbonyl decomposition. Traditional intercalation is electrochemical thus limiting intercalant guests to a single atomic species. We show that multiple zero-valent atoms can be intercalated through this chemical route into the host lattice of a 2D crystal. Intermetallic species exhibit unique structural ordering demonstrated in a variety of superlattice diffraction patterns. We believe this method is general and can be used to achieve a wide variety of new 2D materials previously inaccessible. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2015 holdings: @attributes: islocal: N |
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