Influence of Backbone Fluorination in Regioregular Poly(3-alkyl-4-fluoro)thiophenes.

We report two strategies toward the synthesis of 3-alkyl-4-fluorothiophenes containing straight (hexyl and octyl) and branched (2-ethylhexyl) alkyl groups. We demonstrate that treatment of the dibrominated monomer with 1 equiv of alkyl Grignard reagent leads to the formation of a single regioisomer...

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Publicado en:	Journal of the American Chemical Society Vol. 137; no. 21; pp. 6866 - 6880
Autores principales:	Zhuping Fei, Boufflet, Pierre, Wood, Sebastian, Wade, Jessica, Moriarty, John, Gann, Eliot, Ratcliff, Erin L., McNeill, Christopher R., Sirringhaus, Henning, Ji-Seon Kim, Heeney, Martin
Formato:	Artículo
Publicado:	American Chemical Society 6/3/2015
Materias:	Fluorination Polythiophenes Density functional theory Alkyl compounds Polymerization Fluorine
Acceso en línea:	Ver este registro en EBSCOhost