Possible mechanisms of fullerene C 60 antioxidant action.

Novel mechanism of antioxidant activity of buckminsterfullerene C¿¿ based on protons absorbing and mild uncoupling of mitochondrial respiration and phosphorylation was postulated. In the present study we confirm this hypothesis using computer modeling based on Density Functional Theory. Fullerene's...

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Publicado en:BioMed Research International Vol. 2013; pp. 821498 - 821499
Autores principales: Chistyakov, V A, Smirnova, Yu O, Prazdnova, E V, Soldatov, A V
Formato: research Journal Article
Publicado: Wiley-Blackwell 2013
Acceso en línea:Ver este registro en EBSCOhost
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      dt: 2013
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      pub: Wiley-Blackwell
      place: Malden, Massachusetts
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        atl: Possible mechanisms of fullerene C 60 antioxidant action.
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        au:
          Chistyakov, V A
          Smirnova, Yu O
          Prazdnova, E V
          Soldatov, A V
        affil: Research Institute of Biology, Southern Federal University, Rostov-on-Don 344090, Russia.
      sug:
        subj:
          Antioxidants Therapeutic Use
          Carbon Therapeutic Use
          Mitochondria Metabolism
          Antioxidants Metabolism
          Carbon Metabolism
          Human
          Mitochondria Drug Effects
          Mitochondria Physiology
          Oxidation-Reduction
          Metabolism Drug Effects
          Protons
          Reactive Oxygen Species Metabolism
          Respiration Drug Effects
      ab: Novel mechanism of antioxidant activity of buckminsterfullerene C¿¿ based on protons absorbing and mild uncoupling of mitochondrial respiration and phosphorylation was postulated. In the present study we confirm this hypothesis using computer modeling based on Density Functional Theory. Fullerene's geroprotective activity is sufficiently higher than those of the most powerful reactive oxygen species scavengers. We propose here that C¿¿ has an ability to acquire positive charge by absorbing inside several protons and this complex could penetrate into mitochondria. Such a process allows for mild uncoupling of respiration and phosphorylation. This, in turn, leads to the decrease in ROS production.
      pubtype: Academic Journal
      doctype:
        research
        Journal Article
      ougenre: Article
    language: English
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