Differential capture of serum proteins for expression profiling and biomarker discovery in pre- and posttreatment head and neck cancer samples.

Introduction: A long-term goal of our group is to develop proteomic-based approaches to the detection and use of protein biomarkers for improvement in diagnosis, prognosis, and tailoring of treatment for head and neck squamous cell cancer (HNSCC). We have previously demonstrated that protein express...

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Publicado en:Laryngoscope Vol. 118; no. 1; pp. 61 - 69
Autores principales: Freed GL, Cazares LH, Fichandler CE, Fuller TW, Sawyer CA, Stack BC Jr., Schraff S, Semmes OJ, Wadsworth JT, Drake RR, Freed, Gary L, Cazares, Lisa H, Fichandler, Craig E, Fuller, Thomas W, Sawyer, Christopher A, Stack, Brendan C Jr, Schraff, Scott, Semmes, O John, Wadsworth, J Trad, Drake, Richard R
Formato: research tables/charts tracings Journal Article
Publicado: Wiley-Blackwell 2008
Acceso en línea:Ver este registro en EBSCOhost
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        atl: Differential capture of serum proteins for expression profiling and biomarker discovery in pre- and posttreatment head and neck cancer samples.
      aug:
        au:
          Freed GL
          Cazares LH
          Fichandler CE
          Fuller TW
          Sawyer CA
          Stack BC Jr.
          Schraff S
          Semmes OJ
          Wadsworth JT
          Drake RR
          Freed, Gary L
          Cazares, Lisa H
          Fichandler, Craig E
          Fuller, Thomas W
          Sawyer, Christopher A
          Stack, Brendan C Jr
          Schraff, Scott
          Semmes, O John
          Wadsworth, J Trad
          Drake, Richard R
        affil: Department of Microbiology and Molecular Cell Biology, Center for Biomedical Proteomics, Eastern Virginia Medical School, 700 W. Olney Road, Norfolk, VA 23507, U.S.A
      sug:
        subj:
          Blood Proteins Analysis
          Carcinoma, Squamous Cell Therapy
          Genetic Techniques Methods
          Head and Neck Neoplasms Therapy
          Tumor Markers, Biological Blood
          Affinity Labels Diagnostic Use
          Aged
          Aged, 80 and Over
          Algorithms
          Biological Markers Blood
          Carcinoma, Squamous Cell Blood
          Case Control Studies
          Descriptive Statistics
          Female
          Funding Source
          Head and Neck Neoplasms Blood
          Information Science
          Male
          Middle Age
          Molecular Probe Techniques
          Neoplasm Staging
          Prognosis
          Prospective Studies
          Sample Size
          Smoking Blood
          Software
          Mass Spectrometry
          Human
          Aged: 65+ years
          Aged, 80 & over
          Middle Aged: 45-64 years
          Female
          Male
      ab: Introduction: A long-term goal of our group is to develop proteomic-based approaches to the detection and use of protein biomarkers for improvement in diagnosis, prognosis, and tailoring of treatment for head and neck squamous cell cancer (HNSCC). We have previously demonstrated that protein expression profiling of serum can identify multiple protein biomarker events that can serve as molecular fingerprints for the assessment of HNSCC disease state and prognosis.Methods: An automated Bruker Daltonics (Billerica, MA) ClinProt matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) mass spectrometer was used. Magnetic chemical affinity beads were used to differentially capture serum proteins prior to MALDI-TOF analysis. The resulting spectra were analyzed using postprocessing software and a pattern recognition genetic algorithm (ClinProt 2.0). An HNSCC cohort of 48 sera samples from 24 patients consisting of matched pretreatment and 6 to 12 month posttreatment samples was used for further analysis. Low-mass differentially expressed peptides were identified using MALDI-TOF/TOF.Results: In the working mass range of 1,000 to 10,000 m/z, approximately 200 peaks were resolved for ionic bead capture approaches. For spectra generated from weak cation bead capture, a k-nearest neighbor genetic algorithm was able to correctly classify 94% normal from pretreatment HNSCC samples, 80% of pretreatment from posttreatment samples, and 87% of normal from posttreatment samples. These peptides were then analyzed by MALDI-TOF/TOF mass spectometry for sequence identification directly from serum processed with the same magnetic bead chemistry or alternatively after gel electrophoresis separation of the captured proteins. We were able to compare this with similar studies using surface-enhanced laser desorption ionization (SELDI)-TOF to show this method as a valid tool for this process with some improvement in the identification of our groups.Conclusions: This initial study using new high-resolution MALDI-TOF mass spectrometry coupled with bead fractionation is suitable for automated protein profiling and has the capability to simultaneously identify potential biomarker proteins for HNSCC. In addition, we were able to show improvement with the MALDI-TOF in identifying groups with HNSCC when compared with our prior data using SELDI-TOF. Using this MALDI-TOF technology as a discovery platform, we anticipate generating biomarker panels for use in more accurate prediction of prognosis and treatment efficacies for HNSCC.
      pubtype: Academic Journal
      doctype:
        research
        tables/charts
        tracings
        Journal Article
      ougenre: Article
    language: English
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