Origin of Fast Catalysis in Allylic Amination Reactions Catalyzed by Pd-Ti Heterobimetallic Complexes.

Experiments and density functional calculations were used to quantify the impact of the Pd--Ti interaction in the cationic heterobimetallic ClTi(NBuPPh)Pd(η³-methallyl) catalyst 1 used for allylic aminations. The catalytic significance of the Pd--Ti interaction was evaluated computationally by exami...

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Publicado en:	Journal of the American Chemical Society Vol. 137; no. 23; pp. 7371 - 7379
Autores principales:	Walker, Whitney K., Kay, Benjamin M., Michaelis, Scott A., Anderson, Diana L., Smith, Stacey J., Ess, Daniel H., Michaelis, David J.
Formato:	Artículo
Publicado:	American Chemical Society 6/17/2015
Materias:	Heterobimetallic complexes Allylic amination Metal complexes Organic synthesis Catalysis
Acceso en línea:	Ver este registro en EBSCOhost