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Metal-Organic Nanotube with Helical and Propeller-Chiral Motifs Composed of a C-Symmetric Double-Decker Nanoring.

Coassembly of an achiral ferrocene-cored tetratopic pyridyl ligand (FcL) with AgBF in CHCl/ MeCN (7:3 v/v) containing chiral BuN (+)- or (--)-menthylsulfate (MS ) results in the formation of an "optically active" metal--organic nanotube (FcNT) composed of a C-symmetric double-decker nanoring featuri...

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Published in:Journal of the American Chemical Society Vol. 137; no. 24; pp. 7628 - 7632
Main Authors: Hiroshi Yamagishi, Takahiro Fukino, Daisuke Hashizume, Tadashi Mori, Yoshihisa Inoue, Takaaki Hikima, Masaki Takata, Takuzo Aida
Format: Article
Published: American Chemical Society 6/24/2015
Subjects:
Nanotubes
Spectroscopic imaging
Polymers
Ligands (Chemistry)
Macrocyclic compounds
Online Access:View this record in EBSCOhost