Luminescent Ce(III) Complexes as Stoichiometric and Catalytic Photoreductants for Halogen Atom Abstraction Reactions.

Luminescent Ce(III) complexes, Ce[N(SiMe)] (1) and [(MeSi)NC(RN)]Ce[N(SiMe)] (R = Pr, Pr; R = Cy, 1-Cy), with C and C solution symmetries display absorptive 4f → 5d electronic transitions in the visible region. Emission bands are observed at 553, 518, and 523 nm for 1, Pr, and 1-Cy with lifetimes of...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 137; no. 29; pp. 9234 - 9238
Main Authors:	Haolin Yin, Carroll, Patrick J., Anna, Jessica M., Schelter, Eric J.
Format:	Article
Published:	American Chemical Society 7/29/2015
Subjects:	Halogens Abstraction reactions Photosensitizers Metathesis reactions Density functional theory Abstraction process (Catalysis)
Online Access:	View this record in EBSCOhost