Mechanically Interlocked Linkers inside Metal-Organic Frameworks: Effect of Ring Size on Rotational Dynamics.

A series of metal-organic framework (MOF) materials has been prepared, each containing a mechanically interlocked molecule (MIM) as the linker and a copper(II) paddlewheel as the secondary building unit (SBU). The MIM linkers are [2]rotaxanes with varying sizes of crown ether macrocycles ([22]crown-...

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Publicado en:	Journal of the American Chemical Society Vol. 137; no. 30; pp. 9643 - 9652
Autores principales:	Vukotic, V. Nicholas, O'Keefe, Christopher A., Kelong Zhu, Harris, Kristopher J., To, Christine, Schurko, Robert W., Loeb, Stephen J.
Formato:	Artículo
Publicado:	American Chemical Society 8/5/2015
Materias:	Metal-organic frameworks Copper Structural frames Native element minerals X-rays
Acceso en línea:	Ver este registro en EBSCOhost