Activation of Dioxygen by a TAML Activator in Reverse Micelles: Characterization of an FeFe Dimer and Associated Catalytic Chemistry.

Iron TAML activators of peroxides are functional catalase-peroxidase mimics. Switching from hydrogen peroxide (HO) to dioxygen (O) as the primary oxidant was achieved by using a system of reverse micelles of Aerosol OT (AOT) in n-octane. Hydrophilic TAML activators are localized in the aqueous micro...

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Publicado en:	Journal of the American Chemical Society Vol. 137; no. 30; pp. 9704 - 9716
Autores principales:	Tang, Liang L., Gunderson, William A., Weitz, Andrew C., Hendrich, Michael P., Ryabov, Alexander D., Collins, Terrence J.
Formato:	Artículo
Publicado:	American Chemical Society 8/5/2015
Materias:	Reversed micelles Oxygen Photochemistry Micelles Refrigerants
Acceso en línea:	Ver este registro en EBSCOhost