High-Yield Exfoliation of Ultrathin Two-Dimensional Ternary Chalcogenide Nanosheets for Highly Sensitive and Selective Fluorescence DNA Sensors.

High-yield preparation of ultrathin two-dimensional (2D) nanosheets is of great importance for the further exploration of their unique properties and promising applications. Herein, for the first time, the high-yield and scalable production of ultrathin 2D ternary chalcogenide nanosheets, including...

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Publicado en:Journal of the American Chemical Society Vol. 137; no. 32; pp. 10430 - 10437
Autores principales: Chaoliang Tan, Peng Yu, Yanling Hu, Junze Chen, Ying Huang, Yongqing Cai, Zhimin Luo, Bing Li, Qipeng Lu, Lianhui Wang, Zheng Liu, Hua Zhang
Formato: Artículo
Publicado: American Chemical Society 8/19/2015
Materias:
Acceso en línea:Ver este registro en EBSCOhost
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      dt: 8/19/2015
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      pub: American Chemical Society
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        10.1021/jacs.5b06982
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        atl: High-Yield Exfoliation of Ultrathin Two-Dimensional Ternary Chalcogenide Nanosheets for Highly Sensitive and Selective Fluorescence DNA Sensors.
      aug:
        au:
          Chaoliang Tan
          Peng Yu
          Yanling Hu
          Junze Chen
          Ying Huang
          Yongqing Cai
          Zhimin Luo
          Bing Li
          Qipeng Lu
          Lianhui Wang
          Zheng Liu
          Hua Zhang
        affil:
          School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore
          Key Laboratory for Organic Electronics and Information Display (KLOEID) and Institute of Advanced Materials (LAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing University of Posts and Telecommunications, 9 Wenyuan Road, Nanjing 210046, China
          Institute of High Performance Computing, STAR (Agency for Science, Technology and Research) 1 Fusionopolis Way, Singapore 138632, Singapore
          Institute of Materials Research and Engineering, STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602, Singapore
      su:
        Chalcogenide films
        Fluorescence
        Detectors
        Deoxyribose
        Optical properties
      sug:
        subj:
          Chalcogenide films
          Fluorescence
          Detectors
          Deoxyribose
          Optical properties
      ab: High-yield preparation of ultrathin two-dimensional (2D) nanosheets is of great importance for the further exploration of their unique properties and promising applications. Herein, for the first time, the high-yield and scalable production of ultrathin 2D ternary chalcogenide nanosheets, including TaNiS and TaNiSe, in solution is achieved by exfoliating their layered microflakes. The size of resulting TaNiS and TaNiS nanosheets ranges from tens of nanometers to few micrometers. Importantly, the production yield of single-layer TaNiS nanosheets is very high, ca. 86%. As a proof-of-concept application, the single-layer TaNiS is used as a novel fluorescence sensing platform for the detection of DNA with excellent selectivity and high sensitivity (with detection limit of 50 pM). These solution-processable, high-yield, large-amount ternary chalcogenide nanosheets may also have potential applications in electrocatalysis, supercapacitors, and electronic devices.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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