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Co-Carbene Radical Approach to Substituted 1H-Indenes.

A new strategy for the catalytic synthesis of substituted 1H-indenes via metalloradical activation of o-cinnamyl N-tosyl hydrazones is presented, taking advantage of the intrinsic reactivity of a Co carbene radical intermediate. The reaction uses readily available starting materials and is operation...

Full description

Published in:Journal of the American Chemical Society Vol. 138; no. 28; pp. 8968 - 8976
Main Authors: Das, Braja Gopal, Chirila, Andrei, Tromp, Moniek, Reek, Joost N. H., de Bruin, Bas
Format: Article
Published: American Chemical Society 7/20/2016
Subjects:
Carbenes
Indene
Hydrazones
Catalytic activity
Substrates (Materials science)
Density functional theory
Online Access:View this record in EBSCOhost