Two-State Reactivity Mechanism of Benzene C-C Activation by Trinuclear Titanium Hydride.

The cleavage of inert C-C bonds is a central challenge in modern chemistry. Multinuclear transition metal complexes would be a desirable alternative because of the synergetic effect of multiple metal centers. In this work, carbon-carbon bond cleavage and rearrangement of benzene by a trinuclear tita...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 138; no. 35; pp. 11069 - 11073
Main Authors:	Bo Zhu, Wei Guan, Li-Kai Yan, Zhong-Min Su
Format:	Article
Published:	American Chemical Society 9/7/2016
Subjects:	Reaction mechanisms (Chemistry) Carbon-carbon bonds Titanium hydride Activation (Chemistry) Density functional theory
Online Access:	View this record in EBSCOhost