Combined Ligand/Structure-Based Virtual Screening and Molecular Dynamics Simulations of Steroidal Androgen Receptor Antagonists.

The antiandrogens, such as bicalutamide, targeting the androgen receptor (AR), are the main endocrine therapies for prostate cancer (PCa). But as drug resistance to antiandrogens emerges in advanced PCa, there presents a high medical need for exploitation of novel AR antagonists. In this work, the r...

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Publicado en:BioMed Research International Vol. 2017; pp. 1 - 19
Autores principales: Wang, Yuwei, Han, Rui, Zhang, Huimin, Liu, Hongli, Li, Jiazhong, Liu, Huanxiang, Gramatica, Paola
Formato: equations & formulas pictorial research tables/charts Journal Article
Publicado: Wiley-Blackwell 2/15/2017
Acceso en línea:Ver este registro en EBSCOhost
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      dt: 2/15/2017
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      pub: Wiley-Blackwell
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        10.1155/2017/3572394
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        atl: Combined Ligand/Structure-Based Virtual Screening and Molecular Dynamics Simulations of Steroidal Androgen Receptor Antagonists.
      aug:
        au:
          Wang, Yuwei
          Han, Rui
          Zhang, Huimin
          Liu, Hongli
          Li, Jiazhong
          Liu, Huanxiang
          Gramatica, Paola
        affil: School of Pharmacy, Lanzhou University, 199 West Donggang Rd., Lanzhou 730000, China
      sug:
        subj:
          Virtual High-Throughput Screening Utilization
          Ligands
          Androgen Antagonists
          Italy
          Human
          Male
          Molecular Structure
          Prostatic Neoplasms
          Descriptive Statistics
          Funding Source
          Male
      ab: The antiandrogens, such as bicalutamide, targeting the androgen receptor (AR), are the main endocrine therapies for prostate cancer (PCa). But as drug resistance to antiandrogens emerges in advanced PCa, there presents a high medical need for exploitation of novel AR antagonists. In this work, the relationships between the molecular structures and antiandrogenic activities of a series of 7α-substituted dihydrotestosterone derivatives were investigated. The proposed MLR model obtained high predictive ability. The thoroughly validated QSAR model was used to virtually screen new dihydrotestosterones derivatives taken from PubChem, resulting in the finding of novel compounds CID_70128824, CID_70127147, and CID_70126881, whose in silico bioactivities are much higher than the published best one, even higher than bicalutamide. In addition, molecular docking, molecular dynamics (MD) simulations, and MM/GBSA have been employed to analyze and compare the binding modes between the novel compounds and AR. Through the analysis of the binding free energy and residue energy decomposition, we concluded that the newly discovered chemicals can in silico bind to AR with similar position and mechanism to the reported active compound and the van der Waals interaction is the main driving force during the binding process.
      pubtype: Academic Journal
      doctype:
        equations & formulas
        pictorial
        research
        tables/charts
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      ougenre: Article
    language: English
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