Unearthing a Well-Defined Highly Active Bimetallic W/Ti Precatalyst Anchored on a Single Silica Surface for Metathesis of Propane.

Two compatible organometallic complexes, W(Me) (1) and TiNp (2), were successively anchored on a highly dehydroxylated single silica support (SiO) to synthesize the well-defined bimetallic precatalyst [(?Si-O-)W(Me)(?Si-O-)Ti(Np)] (4). Precatalyst 4 was characterized at the molecular level using adv...

Descripción completa

Detalles Bibliográficos

Publicado en:	Journal of the American Chemical Society Vol. 139; no. 9; pp. 3522 - 3528
Autores principales:	Samantaray, Manoja K., Kavitake, Santosh, Morlanés, Natalia, Abou-Hamad, Edy, Hamieh, Ali, Dey, Raju, Basset, Jean-Marie
Formato:	Resumen
Publicado:	American Chemical Society 3/8/2017
Materias:	Metals Propane Silica
Acceso en línea:	Ver este registro en EBSCOhost