Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4).
Tetra(o-tolyl)diborane(4), 1, was synthesized and characterized experimentally as well as theoretically by density functional theory (DFT) calculations. Exposure of 1 to H (1 bar) at room temperature afforded the corresponding di(o-tolyl)hydroborane through cleavage of the H-H and B-B bonds. DFT cal...
| Publicado en: | Journal of the American Chemical Society Vol. 139; no. 7; pp. 2593 - 2597 |
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| Autores principales: | , , , , |
| Formato: | Artículo |
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American Chemical Society
2/22/2017
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=123637696&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 123637696 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 2/22/2017 vid: 139 iid: 7 pid: 997 pub: American Chemical Society artinfo: ui: 123637696 10.1021/jacs.7b00924 ppf: 2593 ppct: 4 formats: tig: atl: Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4). aug: au: Tsukahara, Nana Hiroki Asakawa Ka-Ho Lee Zhenyang Lin Makoto Yamashita affil: Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, 112-8551 Tokyo, Japan Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon 999077, Hong Kong Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8603 Aichi, Japan Research Development Initiative, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, 112-8551 Tokyo, Japan su: Scission (Chemistry) Dihydrogen bonding Density functional theory Borane derivatives Anion analysis sug: subj: Scission (Chemistry) Dihydrogen bonding Density functional theory Borane derivatives Anion analysis ab: Tetra(o-tolyl)diborane(4), 1, was synthesized and characterized experimentally as well as theoretically by density functional theory (DFT) calculations. Exposure of 1 to H (1 bar) at room temperature afforded the corresponding di(o-tolyl)hydroborane through cleavage of the H-H and B-B bonds. DFT calculations suggested a diarylboryl anion character for the transition state. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2017 holdings: @attributes: islocal: N |
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