Use of wastewater treatment plant biogas for the operation of Solid Oxide Fuel Cells (SOFCs).

Solid Oxide Fuel Cells (SOFCs) perform well on light hydrocarbon fuels, and the use of biogas derived from the anaerobic digestion (AD) of municipal wastewater sludges could provide an opportunity for the CH 4 produced to be used as a renewable fuel. Greenhouse gas (GHG), NO x , SO x , and hydrocarb...

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Published in:Journal of Environmental Management Vol. 203; pp. 753 - 760
Main Authors: Lackey, Jillian, Champagne, Pascale, Peppley, Brant
Format: Article
Published: Academic Press Inc. Dec2017 Part 2
Subjects:
Online Access:View this record in EBSCOhost
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        03014797
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      dt: Dec2017 Part 2
      vid: 203
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      pub: Academic Press Inc.
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        125057294
        10.1016/j.jenvman.2016.09.006
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        atl: Use of wastewater treatment plant biogas for the operation of Solid Oxide Fuel Cells (SOFCs).
      aug:
        au:
          Lackey, Jillian
          Champagne, Pascale
          Peppley, Brant
        affil:
          Department of Civil Engineering, Queen's University, Ellis Hall, 58 University Ave., Kingston, ON, K7L 3N6, Canada
          Queen's – RMC Fuel Cell Research Centre, Queen's Innovation Park, 945 Princess Street, Second Floor, Kingston, ON, K7L 3N6, Canada
          Department of Chemical Engineering, Queen's University, 19 Division St., Kingston, ON, K7L 3N6, Canada
      su:
        Sewage disposal plants
        Solid oxide fuel cells
        Anaerobic digestion
        Humidity control
        Biogas
      sug:
        subj:
          Electrical Contractors and Other Wiring Installation Contractors
          Waste treatment and disposal
          Solid Waste Landfill
          Sewage Treatment Facilities
          Water and Sewer Line and Related Structures Construction
          Sewage disposal plants
          Solid oxide fuel cells
          Anaerobic digestion
          Humidity control
          Biogas
      keyword:
        Renewable
        Solid oxide fuel cell
        Wastewater treatment
        Renewable
        Solid oxide fuel cell
        Wastewater treatment
      ab: Solid Oxide Fuel Cells (SOFCs) perform well on light hydrocarbon fuels, and the use of biogas derived from the anaerobic digestion (AD) of municipal wastewater sludges could provide an opportunity for the CH 4 produced to be used as a renewable fuel. Greenhouse gas (GHG), NO x , SO x , and hydrocarbon pollutant emissions would also be reduced. In this study, SOFCs were operated on AD derived biogas. Initially, different H 2 dilutions were tested (N 2 , Ar, CO 2 ) to examine the performance of tubular SOFCs. With inert gases as diluents, a decrease in cell performance was observed, however, the use of CO 2 led to a higher decrease in performance as it promoted the reverse water-gas shift (WGS) reaction, reducing the H 2 partial pressure in the gas mixture. A model was developed to predict system efficiency and GHG emissions. A higher electrical system efficiency was noted for a steam:carbon ratio of 2 compared to 1 due to the increased H 2 partial pressure in the reformate resulting from higher H 2 O concentration. Reductions in GHG emissions were estimated at 2400 tonnes CO 2 , 60 kg CH 4 and 18 kg N 2 O. SOFCs were also tested using a simulated biogas reformate mixture (66.7% H 2 , 16.1% CO, 16.5% CO 2 , 0.7% N 2 , humidified to 2.3 or 20 mol% H 2 O). Higher humidification yielded better performance as the WGS reaction produced more H 2 with additional H 2 O. It was concluded that AD-derived biogas, when cleaned to remove H 2 S, Si compounds, halides and other contaminants, could be reformed to provide a clean, renewable fuel for SOFCs.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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