A N-Heterocyclic Carbene-Stabilized Coinage Metal-Chalcogenide Framework with Tunable Optical Properties.

A new class of coinage-metal chalcogenide compounds [AuM(μ-E)(IPr)] (M = Ag, Au; E = S, Se, Te) has been synthesized from the combination of Nheterocyclic carbene-ligated gold(I) trimethylsilylchalcogenolates [(IPr)AuESiMe] and ligand-supported metal acetates. Phosphorescence is observed from these...

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Publicado en:	Journal of the American Chemical Society Vol. 139; no. 40; pp. 14045 - 14049
Autores principales:	Polgar, Alexander M., Weigend, Florian, Zhang, Angel, Stillman, Martin J., Corrigan, John F.
Formato:	Artículo
Publicado:	American Chemical Society 10/11/2017
Materias:	Chalcogenides Carbenes Density functional theory Ligands (Chemistry) Chalcogens Coinage
Acceso en línea:	Ver este registro en EBSCOhost