Hetero Cu(III)--Pd(II) Complex of a Dibenzo[g,p]chrysene-Fused Bisdicarbacorrole with Stable Organic Radical Character.

Bis-dicarbacorrole (bis-H) with two adj-CCNN subunits was synthesized by incorporating a dibenzo[g,p]chrysene moiety into the macrocyclic structure. The two trianionic cores in bis-H can stabilize two Cu(III) ions (bis-Cu) or concurrently a Cu(III) cation and a Pd(II) ion in the form of a hetero bis...

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Publicado en:	Journal of the American Chemical Society Vol. 139; no. 42; pp. 15232 - 15239
Autores principales:	Xian-Sheng Ke, Yongseok Hong, Peiyu Tu, Qing He, Lynch, Vincent M., Dongho Kim, Sessler, Jonathan L.
Formato:	Artículo
Publicado:	American Chemical Society 10/25/2017
Materias:	Chrysene Electron paramagnetic resonance spectroscopy Cyclic voltammetry Density functional theory Current density (Electromagnetism)
Acceso en línea:	Ver este registro en EBSCOhost