Palladium-Catalyzed Cyclization: Regioselectivity and Structure of Arene-Fused C Derivatives.

The palladium-catalyzed cyclization on the fullerene C cage has been achieved using several aryl halides and C. This reaction was found to be accelerated by the addition of pivalic acid, which can be rationally explained by the computational study based on the concerted metalation-deprotonation mech...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 139; no. 45; pp. 16350 - 16359
Main Authors:	Yoshifumi Hashikawa, Atsushi Wakamiya, Yasujiro Murata
Format:	Article
Published:	American Chemical Society 11/15/2017
Subjects:	Palladium Ring formation (Chemistry) Nuclear magnetic resonance Density functional theory Hydrogen bonding
Online Access:	View this record in EBSCOhost