Non-Metal-Catalyzed Heterodehydrocoupling of Phosphines and Hydrosilanes: Mechanistic Studies of B(CF)-Mediated Formation of P-Si Bonds.

Non-metal-catalyzed heterodehydrocoupling of primary and secondary phosphines (RRPH, R = H or R) with hydrosilanes (RRRSiH, R, R = H or R) to produce synthetically useful silylphosphines (RRP-SiRRR) has been achieved using B(CF) as the catalyst (10 mol %, 100 °C). Kinetic studies demonstrated that t...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 139; no. 46; pp. 16780 - 16791
Main Authors:	Lipeng Wu, Chitnis, Saurabh S., Haijun Jiao, Annibale, Vincent T., Manners, Ian
Format:	Article
Published:	American Chemical Society 11/22/2017
Subjects:	Phosphines Silane Chemical reactions Density functional theory Chemical bonds Nucleophilic reactions
Online Access:	View this record in EBSCOhost