Origins of Enantioselectivity in Asymmetric Radical Additions to Octahedral Chiral-at-Rhodium Enolates: A Computational Study.

The origin of asymmetric induction in the additions of carbon- and nitrogen-centered radicals to octahedral centrochiral rhodium enolates has been investigated with density functional theory calculations. Computed free energies of activation reproduce the preference for the experimentally observed m...

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Publicado en:	Journal of the American Chemical Society Vol. 139; no. 49; pp. 17902 - 17908
Autores principales:	Shuming Chen, Xiaoqiang Huang, Meggers, Eric, Houk, K. N.
Formato:	Artículo
Publicado:	American Chemical Society 12/13/2017
Materias:	Rhodium compounds Enantioselective catalysis Addition reactions Asymmetric synthesis Enolates Density functional theory
Acceso en línea:	Ver este registro en EBSCOhost