High-Energy-Resolution Fluorescence-Detected X‑ray Absorption of the Q Intermediate of Soluble Methane Monooxygenase.

Kα high-energy-resolution fluorescence detected X-ray absorption spectroscopy (HERFD XAS) provides a powerful tool for overcoming the limitations of conventional XAS to identify the electronic structure and coordination environment of metalloprotein active sites. Herein, Fe Kα HERFD XAS is applied t...

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Publicado en:	Journal of the American Chemical Society Vol. 139; no. 49; pp. 18024 - 18034
Autores principales:	Castillo, Rebeca G., Banerjee, Rahul, Allpress, Caleb J., Rohde, Gregory T., Bill, Eckhard, Que, Jr.,, Lawrence, Lipscomb, John D., DeBeer, Serena
Formato:	Artículo
Publicado:	American Chemical Society 12/13/2017
Materias:	Methane monooxygenase Iron compounds X-ray absorption Intermediates (Chemistry) Density functional theory Catalytic oxidation
Acceso en línea:	Ver este registro en EBSCOhost