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Regio- and Chemoselective Hydrogenation of Dienes to Monoenes Governed by a Well-Structured Bimetallic Surface.

Unprecedented surface chemistry, governed by specific atomic arrangements and the steric effect of ordered alloys, is reported. Rh-based ordered alloys supported on SiO (RhM/SiO, M = Bi, Cu, Fe, Ga, In, Pb, Sn, and Zn) were prepared and tested as catalysts for selective hydrogenation of trans-1,4-he...

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Published in:Journal of the American Chemical Society Vol. 139; no. 50; pp. 18231 - 18240
Main Authors: Masayoshi Miyazaki, Shinya Furukawa, Takayuki Komatsu
Format: Article
Published: American Chemical Society 12/20/2017
Subjects:
Surface chemistry
Hydrogenation
Regioselectivity (Chemistry)
Rhodium alloys
Density functional theory
Online Access:View this record in EBSCOhost

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