Cooperative Bond Scission in a Soft Porous Crystal Enables Discriminatory Gate Opening for Ethylene over Ethane.

Here we report a soft porous crystal possessing hemilabile cross-links in its framework that exhibits exclusive gate opening for ethylene, enabling the discriminatory adsorption of ethylene over ethane. A Co-based porous coordination polymer (PCP) bearing vinylogous tetrathiafulvalene (VTTF) ligands...

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Publicado en:	Journal of the American Chemical Society Vol. 139; no. 50; pp. 18313 - 18322
Autores principales:	Sen, Susan, Nobuhiko Hosono, Jia-Jia Zheng, Shinpei Kusaka, Ryotaro Matsuda, Shigeyoshi Sakaki, Susumu Kitagawa
Formato:	Artículo
Publicado:	American Chemical Society 12/20/2017
Materias:	Ethylene synthesis Scission (Chemistry) Adsorption capacity Intermolecular interactions Density functional theory
Acceso en línea:	Ver este registro en EBSCOhost