Energetics of van der Waals Adsorption on the Metal-Organic Framework NU-1000 with Zr-oxo, Hydroxo, and Aqua Nodes.

We report measurements of adsorption isotherms and the determination of the isosteric heats of adsorption of several small gases (H2, D2, Ne, N2, CO, CH4,C2H6, Ar, Kr, and Xe) on the metal-organic framework (MOF) NU-1000, which is one of the most thermally stable MOFs. It has transition-metal nodes...

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Publicado en:	Journal of the American Chemical Society Vol. 140; no. 1; pp. 328 - 339
Autores principales:	Zhang, Wei, Ma, Yuanyuan, Santos-Lopez, Iván A., Lownsbury, James M., Yu, Haoyu, Liu, Wei-Guang, Truhlar, Donald G., Campbell, Charles T., Vilches, Oscar E.
Formato:	Artículo
Publicado:	American Chemical Society 1/10/2018
Materias:	Metal-organic frameworks Van der Waals forces Adsorption isotherms Transition metal catalysts Benzoates
Acceso en línea:	Ver este registro en EBSCOhost