Metal as Source of Chirality in Octahedral Complexes with Tripodal Tetradentate Ligands.

The challenging control of the absolute configuration of chiral-at-metal complexes is efficiently achieved using the tripodal tetradentate ligand L. The optical resolution of rac-[RhCl(κC,N,N′,P-L)] mediated by (S)-α-phenylglycine provides access to enantiopure complexes of general formula [Rh(κC,N,...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 140; no. 3; pp. 912 - 916
Main Authors:	Carmona, María, Rodríguez, Ricardo, Passarelli, Vincenzo, Lahoz, Fernando J., García-Orduña, Pilar, Carmona, Daniel
Format:	Article
Published:	American Chemical Society 1/24/2018
Subjects:	Metal complexes Chirality Nuclear magnetic resonance spectroscopy Density functional theory Enantioselective catalysis Ligand analysis
Online Access:	View this record in EBSCOhost