Probing Interactions of N-Donor Molecules with Open Metal Sites within Paramagnetic Cr-MIL-101: A Solid-State NMR Spectroscopic and Density Functional Theory Study.

Understanding host-guest interactions is one of the key requirements for adjusting properties in metal- organic frameworks (MOFs). In particular, systems with coordinatively unsaturated Lewis acidic metal sites feature highly selective adsorption processes. This is attributed to strong interactions...

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Publicado en:	Journal of the American Chemical Society Vol. 140; no. 6; pp. 2135 - 2145
Autores principales:	Wittmann, Thomas, Mondal, Arobendo, Tschense, Carsten B. L., Wittmann, Johannes J., Klimm, Ottokar, Siegel, Renée, Corzilius, Björn, Weber, Birgit, Kaupp, Martin, Senker, Juergen
Formato:	Artículo
Publicado:	American Chemical Society 2/14/2018
Materias:	Metal-organic frameworks Density functional theory Diethylamine Thermogravimetry Hyperfine coupling Nuclear magnetic resonance
Acceso en línea:	Ver este registro en EBSCOhost