Thermodynamic Hydricities of Biomimetic Organic Hydride Donors.

Thermodynamic hydricities (ΔG) in acetonitrile and dimethyl sulfoxide have been calculated and experimentally measured for several metal-free hydride donors: NADH analogs (BNAH, CN-BNAH, Me-MNAH, HEH), methylene tetrahydromethanopterin analogs (BIMH, CAFH), acridine derivatives (Ph-AcrH, Me[sub 2]N-...

Full description

Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 140; no. 13; pp. 4569 - 4580
Main Authors:	Ilic, Stefan, Kadel, Usha Pandey, Basdogan, Yasemin, Keith, John A., Glusac, Ksenija D.
Format:	Article
Published:	American Chemical Society 4/4/2018
Subjects:	Transition metal hydrides Dimethyl sulfoxide Acridine derivatives Density functional theory Hydride transfer reactions Acetonitrile
Online Access:	View this record in EBSCOhost