Lewis-Brønsted Acid Pairs in Ga/H-ZSM-5 To Catalyze Dehydrogenation of Light Alkanes.

The active sites for propane dehydrogenation in Ga/H-ZSM-5 with moderate concentrations of tetrahedral aluminum in the lattice were identified to be Lewis -Brønsted acid pairs. With increasing availability, Ga and Brønsted acid site concentrations changed inversely, as protons of Brønsted acid sites...

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Publicado en:	Journal of the American Chemical Society Vol. 140; no. 14; pp. 4849 - 4860
Autores principales:	Schreiber, Moritz W., Plaisance, Craig P., Baumgärtl, Martin, Reuter, Karsten, Jentys, Andreas, Bermejo-Deval, Ricardo, Lercher, Johannes A.
Formato:	Artículo
Publicado:	American Chemical Society 4/11/2018
Materias:	Alkanes Aluminum Dehydrogenation Elimination reactions Aliphatic compounds Tetrahedral molecules Density functional theory
Acceso en línea:	Ver este registro en EBSCOhost