Outer-Sphere Control of Catalysis on Surfaces: A Comparative Study of Ti(IV) Single-Sites Grafted on Amorphous versus Crystalline Silicates for Alkene Epoxidation.

The effect of outer-sphere environment on alkene epoxidation catalysis using an organic hydroperoxide oxidant is demonstrated for calix[4]arene-Ti single-sites grafted on amorphous vs crystalline delaminated zeotype (UCB-4) silicates as supports. A chelating calix[4]arene macrocyclic ligand helps en...

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Publicado en:	Journal of the American Chemical Society Vol. 140; no. 15; pp. 4956 - 4961
Autores principales:	Grosso-Giordano, Nicolás A., Schroeder, Christian, Okrut, Alexander, Solovyov, Andrew, Schhöttle, Christian, Chassé, Walter, Marinkovic, Nebojša, Koller, Hubert, Zones, Stacey I., Katz, Alexander
Formato:	Artículo
Publicado:	American Chemical Society 4/18/2018
Materias:	Catalysis Comparative studies Amorphous substances Silicates Alkenes
Acceso en línea:	Ver este registro en EBSCOhost