NRVS Studies of the Peroxide Shunt Intermediate in a Rieske Dioxygenase and Its Relation to the Native Fe O Reaction.

The Rieske dioxygenases are a major subclass of mononuclear nonheme iron enzymes that play an important role in bioremediation. Recently, a high-spin Fe-(hydro)-peroxy intermediate (BZDOp) has been trapped in the peroxide shunt reaction of benzoate 1,2-dioxygenase. Defining the structure of this int...

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Publicado en:	Journal of the American Chemical Society Vol. 140; no. 16; pp. 5544 - 5560
Autores principales:	Sutherlin, Kyle D., Rivard, Brent S., Böttger, Lars H., Liu, Lei V., Rogers, Melanie S., Srnec, Martin, Kiyoung Park, Yoshitaka Yoda, Shinji Kitao, Yasuhiro Kobayashi, Makina Saito, Makoto Seto, Hu, Michael, Jiyong Zhao, Lipscomb, John D., Solomon, Edward I.
Formato:	Artículo
Publicado:	American Chemical Society 4/25/2018
Materias:	Peroxides Dioxygenases Bioremediation Hydroperoxy radicals Benzoates Iron Density functional theory
Acceso en línea:	Ver este registro en EBSCOhost