A Zirconium Photosensitizer with a Long-Lived Excited State: Mechanistic Insight into Photoinduced Single-Electron Transfer.

Time-resolved emission spectroscopy for the luminescent zirconium complex Zr(PDP)2 (MePDP = 2,6-bis(5-methyl-3-phenyl-1H-pyrrol-2-yl)pyridine) revealed a long-lived excited state with a lifetime τ = 325 ± 10 μs. Computational studies using time-dependent density functional theory were conducted to i...

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Publicado en:	Journal of the American Chemical Society Vol. 140; no. 18; pp. 5934 - 5948
Autores principales:	Zhang, Yu, Lee, Tia S., Petersen, Jeffrey L., Milsmann, Carsten
Formato:	Artículo
Publicado:	American Chemical Society 5/9/2018
Materias:	Zirconium Photosensitizers Photoinduced electron transfer Emission spectroscopy Density functional theory
Acceso en línea:	Ver este registro en EBSCOhost