Arylruthenium(III) Porphyrin-Catalyzed C-H Oxidation and Epoxidation at Room Temperature and [RuV(Por)(O)(Ph)] Intermediate by Spectroscopic Analysis and Density Functional Theory Calculations.

The development of highly active and selective metal catalysts for efficient oxidation of hydrocarbons and identification of the reactive intermediates in the oxidation catalysis are long-standing challenges. In the rapid hydrocarbon oxidation catalyzed by ruthenium(IV) and -(III) porphyrins, the pu...

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Publicado en:	Journal of the American Chemical Society Vol. 140; no. 22; pp. 7032 - 7043
Autores principales:	Shing, Ka-Pan, Cao, Bei, Liu, Yungen, Li, Ming-De, Phillips, David Lee, Chang, Xiao-Yong, Che, Chi-Ming, Lee, Hung Kay
Formato:	Artículo
Publicado:	American Chemical Society 6/6/2018
Materias:	Oxidation Epoxidation Spectroscopic imaging Density functional theory Metal catalysts
Acceso en línea:	Ver este registro en EBSCOhost