Particle and vapor emissions from vat polymerization desktop-scale 3-dimensional printers.

Little is known about emissions and exposure potential from vat polymerization additive manufacturing, a process that uses light-activated polymerization of a resin to build an object. Five vat polymerization printers (three stereolithography (SLA) and two digital light processing (DLP) were evaluat...

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Publicado en:Journal of Occupational & Environmental Hygiene Vol. 16; no. 8; pp. 519 - 532
Autores principales: Stefaniak, A. B., Bowers, L. N., Knepp, A. K., Luxton, T. P., Peloquin, D. M., Baumann, E. J., Ham, J. E., Wells, J. R., Johnson, A. R., LeBouf, R. F., Su, F.-C., Martin, S. B., Virji, M. A.
Formato: CEU equations & formulas pictorial research tables/charts Journal Article
Publicado: Taylor & Francis Ltd Aug2019
Acceso en línea:Ver este registro en EBSCOhost
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      pub: Taylor & Francis Ltd
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        atl: Particle and vapor emissions from vat polymerization desktop-scale 3-dimensional printers.
      aug:
        au:
          Stefaniak, A. B.
          Bowers, L. N.
          Knepp, A. K.
          Luxton, T. P.
          Peloquin, D. M.
          Baumann, E. J.
          Ham, J. E.
          Wells, J. R.
          Johnson, A. R.
          LeBouf, R. F.
          Su, F.-C.
          Martin, S. B.
          Virji, M. A.
        affil: National Institute for Occupational Safety and Health, Morgantown, West Virginia
      sug:
        subj:
          Occupational Exposure
          Air Pollutants, Occupational Adverse Effects
          Computer Peripherals
          Printing, Three-Dimensional Standards
          Technology
          Education, Continuing (Credit)
          Aerosols Adverse Effects
          Particulate Matter Adverse Effects
          Descriptive Statistics
          Carcinogens Adverse Effects
          Chromium Adverse Effects
          Nickel Adverse Effects
          Reactive Oxygen Species
          Iron
          Zinc
          Pulmonary Alveoli
          Solvents
      ab: Little is known about emissions and exposure potential from vat polymerization additive manufacturing, a process that uses light-activated polymerization of a resin to build an object. Five vat polymerization printers (three stereolithography (SLA) and two digital light processing (DLP) were evaluated individually in a 12.85 m3 chamber. Aerosols (number, size) and total volatile organic compounds (TVOC) were measured using real-time monitors. Carbonyl vapors and particulate matter were collected for offline analysis using impingers and filters, respectively. During printing, particle emission yields (#/g printed) ranged from 1.3 ± 0.3 to 2.8 ± 2.6 x 108 (SLA printers) and from 3.3 ± 1.5 to 9.2 ± 3.0 x 108 (DLP printers). Yields for number of particles with sizes 5.6 to 560 nm (#/g printed) were 0.8 ± 0.1 to 2.1 ± 0.9 x 1010 and from 1.1 ± 0.3 to 4.0 ± 1.2 x 1010 for SLA and DLP printers, respectively. TVOC yield values (µg/g printed) ranged from 161 ± 47 to 322 ± 229 (SLA printers) and from 1281 ± 313 to 1931 ± 234 (DLP printers). Geometric mean mobility particle sizes were 41.1–45.1 nm for SLA printers and 15.3–28.8 nm for DLP printers. Mean particle and TVOC yields were statistically significantly higher and mean particle sizes were significantly smaller for DLP printers compared with SLA printers (p < 0.05). Energy dispersive X-ray analysis of individual particles qualitatively identified potential occupational carcinogens (chromium, nickel) as well as reactive metals implicated in generation of reactive oxygen species (iron, zinc). Lung deposition modeling indicates that about 15–37% of emitted particles would deposit in the pulmonary region (alveoli). Benzaldehyde (1.0–2.3 ppb) and acetone (0.7–18.0 ppb) were quantified in emissions from four of the printers and 4-oxopentanal (0.07 ppb) was detectable in the emissions from one printer. Vat polymerization printers emitted nanoscale particles that contained potential carcinogens, sensitizers, and reactive metals as well as carbonyl compound vapors. Differences in emissions between SLA and DLP printers indicate that the underlying technology is an important factor when considering exposure reduction strategies such as engineering controls.
      pubtype: Academic Journal
      doctype:
        CEU
        equations & formulas
        pictorial
        research
        tables/charts
        Journal Article
      ougenre: Article
    language: English
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