The C--H Activation of Methane by Laser-Ablated Zirconium Atoms: CH=ZrH, the Simplest Carbene Hydride Complex, Agostic Bonding, and (CH)ZrH.
Reaction of laser-ablated Zr with CH (CH, CD, and CHD) in excess neon during condensation at 5 K forms CH == ZrH, the simplest alkylidene hydride complex, which is identified by infrared absorptions at 1581.0, 1546.2, 757.0, and 634.5 cm. Density functional theory electronic structure calculations u...
| Publicado en: | Journal of the American Chemical Society Vol. 127; no. 1; pp. 465 - 474 |
|---|---|
| Autores principales: | , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
1/12/2005
|
| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |