Where Does the Planar-to-Nonplanar Turnover Occur in Small Gold Clusters?

Several levels of theory, including both Gaussian-based and plane wave density functional theory (DFT), second-order perturbation theory (MP2), and coupled cluster methods (CCSD(T)), are employed to study Au and Au clusters. All methods predict that the lowest energy isomer of Au is planar. For Au,...

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Publicado en:Journal of the American Chemical Society Vol. 127; no. 3; pp. 1049 - 1053
Autores principales: Olson, Ryan M., Varganov, Sergey, Gordon, Mark S., Metiu, Horia, Chretien, Steeve, Piecuch, Piotr, Kowalski, Karol, Kucharski, Stanislaw A., Musial, Monika
Formato: Artículo
Publicado: American Chemical Society 1/26/2005
Materias:
Acceso en línea:Ver este registro en EBSCOhost
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        atl: Where Does the Planar-to-Nonplanar Turnover Occur in Small Gold Clusters?
      aug:
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          Olson, Ryan M.
          Varganov, Sergey
          Gordon, Mark S.
          Metiu, Horia
          Chretien, Steeve
          Piecuch, Piotr
          Kowalski, Karol
          Kucharski, Stanislaw A.
          Musial, Monika
        affil:
          Iowa State University.
          University of California-Santa Barbara.
          Michigan State University.
          Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824, USA.
          University of Silesia.
      su:
        Gold
        Density functionals
        Perturbation theory
        Nuclear isomers
        Nuclides
        Functional analysis
      sug:
        subj:
          Gold
          Density functionals
          Perturbation theory
          Nuclear isomers
          Nuclides
          Functional analysis
      ab: Several levels of theory, including both Gaussian-based and plane wave density functional theory (DFT), second-order perturbation theory (MP2), and coupled cluster methods (CCSD(T)), are employed to study Au and Au clusters. All methods predict that the lowest energy isomer of Au is planar. For Au, both DFT methods predict that the two lowest isomers are planar. In contrast, both MP2 and CCSD(T) predict the lowest Au isomers to be nonplanar.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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