Selective Formation of MSI (M = Sc, Ti, and V).

The article informs that nanostructured materials assembled from finite-sized stable clusters have been extensively sought after since the discovery of C. Fabrication of cluster-assembled materials is dependent upon finding a suitable building block for a cluster that is chemically stable and intera...

Descripción completa

Detalles Bibliográficos
Publicado en:Journal of the American Chemical Society Vol. 127; no. 14; pp. 4998 - 5000
Autores principales: Koyasu, Kiichirou, Akutsu, Minoru, Mitsui, Masaaki, Nakajima, Atsushi
Formato: Artículo
Publicado: American Chemical Society 4/13/2005
Materias:
Acceso en línea:Ver este registro en EBSCOhost
fields @attributes:
  recordID: 1
pdfLink:
plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=16753734&site=ehost-live
header:
  @attributes:
    shortDbName: hlh
    uiTerm: 16753734
    longDbName: Humanities International Complete
    uiTag: AN
  controlInfo:
    bkinfo:
    jinfo:
      jid:
        00027863
        ACS
      jtl: Journal of the American Chemical Society
      issn: 00027863
      maglogo: N
    pubinfo:
      dt: 4/13/2005
      vid: 127
      iid: 14
      pid: 997
      pub: American Chemical Society
    artinfo:
      ui:
        16753734
        10.1021/ja045380t
      ppf: 4998
      ppct: 2
      formats:
      tig:
        atl: Selective Formation of MSI (M = Sc, Ti, and V).
      aug:
        au:
          Koyasu, Kiichirou
          Akutsu, Minoru
          Mitsui, Masaaki
          Nakajima, Atsushi
        affil:
          Department of Chemistry, Faculty of Science & Technology, Keio University, Kohoku-ku, Yokohama 223-8522, Japan.
          CREST, Japan Science and Technology Agency (JST), c/o Department of Chemistry, Keio University, Japan.
      su:
        Nanostructured materials
        Molecular orbitals
        Chemical bonds
        Electrons
        Microclusters
        Silicon
      sug:
        subj:
          Nanostructured materials
          Molecular orbitals
          Chemical bonds
          Electrons
          Microclusters
          Silicon
      ab: The article informs that nanostructured materials assembled from finite-sized stable clusters have been extensively sought after since the discovery of C. Fabrication of cluster-assembled materials is dependent upon finding a suitable building block for a cluster that is chemically stable and interacts weakly with other clusters of the same material. To ensure the chemical stability of a cluster, it is crucial to satisfy a closed electron configuration with a large energy gap between the highest occupied molecular orbital and the lowest unoccupied molecular orbital.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
    refInfo:
    copyright:
      @attributes:
        flag: Y
      dt:
        @attributes:
          year: 2005
    holdings:
      @attributes:
        islocal: N