Magnetic Interactions in Dinuclear MnMn Complexes Covalently Tethered to Organic Radicals: Spectroscopic Models for the SY· State of Photosystem II.

A series of isostructural dimeric manganese complexes of the type [(Medtne)Mn(u-O)(μ- R)](X) have been prepared and characterized. The dimanganese cores of these complexes are rigidly held together by the hexadentate ligand Medtne (Medtne = 1 ,2-bis(4,7-dimethyl-1 ,4,7-triazacyclonon-1- yl)ethane)....

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Publicado en:	Journal of the American Chemical Society Vol. 127; no. 16; pp. 6095 - 6109
Autores principales:	Marlin, Dana S., Bill, Eckhard, Weyhermüller, Thomas, Bothe, Eberhard, Wieghardt, Karl
Formato:	Artículo
Publicado:	American Chemical Society 4/27/2005
Materias:	Chemical reactions Radicals (Chemistry) Magnesium Complex compounds Ligands (Chemistry) Optical diffraction Molecular structure
Acceso en línea:	Ver este registro en EBSCOhost