Polymorphs with Varying Platinum(II)-Thallium(I) Interactions.

The article presents information about polymorphs of molecular substance. These substances usually involve differences in molecular conformation, molecular orientation, or crystal packing, factors, including crystal packing effects. At present, only a limited number of polymorphs are known in which...

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Detalles Bibliográficos
Publicado en:Journal of the American Chemical Society Vol. 127; no. 18; pp. 6512 - 6514
Autores principales: Stork, Jay R., Olmstead, Marilyn M., Balch, Alan L.
Formato: Artículo
Publicado: American Chemical Society 5/11/2005
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Acceso en línea:Ver este registro en EBSCOhost
Descripción
Sumario:The article presents information about polymorphs of molecular substance. These substances usually involve differences in molecular conformation, molecular orientation, or crystal packing, factors, including crystal packing effects. At present, only a limited number of polymorphs are known in which such metallophilic interactions differ within them. Diffraction quality crystals of the red polymorph were removed from the reaction mixture and characterized by single-crystal X-ray crystallography. The article further discusses a portion of the structure of the yellow polyrnorph.