19-Electron Intermediates and Cage-Effects in the Photochemical Disproportionation of [CpW(CO)] with Lewis Bases.

The role of 19-electron intermediates in the photochemical disproportionation of [CpW(CO)] (Cp = CH) with Lewis bases (PR R = OMe, Bu, Ph) is investigated on the ultrafast time scale using femtosecond VIS-pump, IR-probe spectroscopy. Formation of a 19-electron (19e) species CpW(CO) ∙ by coordination...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 127; no. 36; pp. 12555 - 12566
Main Authors:	Cahoon, James F., Kling, Matthias F., Schmatz, Stefan, Harris, Charles B.
Format:	Article
Published:	American Chemical Society 9/14/2005
Subjects:	Photochemistry Hydrogen-ion concentration Spectrum analysis Density functionals Particles (Nuclear physics) Radicals
Online Access:	View this record in EBSCOhost