Mathematical modeling for the potential energy of the aminophenol derivative azomethine molecule via Bezier surfaces and fuzzy inference system.

In this study, we have managed to model the energy surface of the aminophenol derivative azomethine molecule mathematically depending on two torsion angles SC1(C9C10C12N14) and SC2(C2C1C6C11). For this purpose, firstly, discrete data obtained from Density Functional Theory calculations have been con...

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Publicado en:Zeitschrift für Naturforschung Section A: A Journal of Physical Sciences Vol. 80; no. 3; pp. 175 - 184
Autor principal: Ermiş, Temel
Formato: Artículo
Publicado: De Gruyter Mar2025
Materias:
Acceso en línea:Ver este registro en EBSCOhost
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      dt: Mar2025
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      pub: De Gruyter
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        183391392
        10.1515/zna-2024-0189
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        atl: Mathematical modeling for the potential energy of the aminophenol derivative azomethine molecule via Bezier surfaces and fuzzy inference system.
      aug:
        au: Ermiş, Temel
        affil: Department of Mathematics and Computer Sciences, Eskisehir Osmangazi University, 26040, Eskisehir, Türkiye
      su:
        Fuzzy logic
        Fuzzy systems
        Global optimization
        Dihedral angles
        Density functional theory
      sug:
        subj:
          Fuzzy logic
          Fuzzy systems
          Global optimization
          Dihedral angles
          Density functional theory
      keyword:
        03B52
        65D05
        65D17
        90C26
        Bezier surfaces
        blending surface
        data and surface modelling
        DFT
        fuzzy inference system
        global optimization
      ab: In this study, we have managed to model the energy surface of the aminophenol derivative azomethine molecule mathematically depending on two torsion angles SC1(C9C10C12N14) and SC2(C2C1C6C11). For this purpose, firstly, discrete data obtained from Density Functional Theory calculations have been converted into continuous data with the help of the Fuzzy Inference System. Thus, it is possible to calculate energy values for untested data, which are very costly in terms of time to obtain with other methods/experiments. Then, the continuous and non-smooth surface obtained from the fuzzy inference system and representing the energy values of the molecule has been transformed into a differentiable surface with the help of Bezier surfaces. Thus, an objective function has been obtained in which global optimization methods based on the derivative (or gradient) operator could be used.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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          year: 2025
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