DFT STUDY OF BaKN AND BaRbN PEROVSKITES: REVEALING THEIR MECHANICAL, OPTOELECTRONIC, AND MAGNETIC PROPERTIES.

The full-potential linearized augmented plane waves (FP-LAPW) method, which is based entirely on density functional theory (DFT), was used to investigate the structural, electronic, magnetic, optical, and elastic properties of BaXN (X=K, Rb). This method also employs the Perdew-Burke-Ernzerhof gener...

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Published in:Revista Cubana de Física Vol. 41; no. 2; pp. 103 - 113
Main Authors: BENATMANE, SAADIYA, HEZIL-ZIANE, SAMIRA
Format: Article
Published: Universidad de La Habana Dec2024
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      dt: Dec2024
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        atl: DFT STUDY OF BaKN AND BaRbN PEROVSKITES: REVEALING THEIR MECHANICAL, OPTOELECTRONIC, AND MAGNETIC PROPERTIES.
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          BENATMANE, SAADIYA
          HEZIL-ZIANE, SAMIRA
        affil:
          Faculty of Sciences and Technology, Department of Science and Technology, BP227 Abdelhamid Ibn Badis University, 27000, Mostaganem, Algeria
          Laboratory of Modelling and Simulation of Materials Science, Djillali Liabès University of Sidi Bel-Abbès, 22000, Sidi Bel-Abbes, Algeria
      su:
        Poisson's ratio
        Molecular physics
        Atomic physics
        Bulk modulus
        Elasticity
        Elastic constants
      sug:
        subj:
          Poisson's ratio
          Molecular physics
          Atomic physics
          Bulk modulus
          Elasticity
          Elastic constants
      keyword:
        Density-functional theory atomic and molecular physics
        optoelectronic and megentic properties
        Perovskites
        structural properties of materials
        optoelectrónicas y magnéticas
        Perovskitas; Mechanical
        propiedades estructurales de los materiales
        Propiedades mácanicas
        Teoría del funcional de densidad física atómica y molecular
      ab:
        The full-potential linearized augmented plane waves (FP-LAPW) method, which is based entirely on density functional theory (DFT), was used to investigate the structural, electronic, magnetic, optical, and elastic properties of BaXN (X=K, Rb). This method also employs the Perdew-Burke-Ernzerhof generalized gradient approximation (GGA-PBE) and a modified Beck Johnson TB-mBJ potential in the exchange correlation term. When the resulting structural properties were examined, the findings s howed that our compounds are more stable when they are configured as ferromagnetic materials. The total and partial density of state curves were used to assess the contributions of the various bands. Additionally, we discovered that the total magnetic moment is an integer of 6 μB, confirming the half-metallic nature. The mechanical stability of these compounds has been discovered. The elastic parameters are obtained, including the elastic constants, bulk modulus, anisotropy factor, Poisson's ratio, and Pugh's ratio.
        El método de ondas planas aumentadas linealizadas de potencial total (FP-LAPW), que se basa completamente en la teoría funcional de la densidad (DFT), se utilizó para investigar las propiedades estructurales, electrónicas, magnéticas, ópticas y elásticas de BaXN (X= K, Rb). Este método también emplea la aproximación de gradiente generalizado de Perdew-Burke-Ernzerhof (GGA-PBE) y un potencial TB-mBJ de Beck Johnson modificado en el término de correlación de intercambio. Cuando se examinaron las propiedades estructurales resultantes, los hallazgos mostraron que nuestros compuestos son más estables cuando están configurados como materiales ferromagnéticos. Se utilizaron curvas de densidad total y parcial de estados para evaluar las contribuciones de las distintas bandas. Además, descubrimos que el momento magnético total es un número entero de 6 B, lo que confirma I a naturaleza semimetálica. Se ha descubierto la estabilidad mecánica de estos compuestos. Se obtienen los parámetros elásticos, incluidas las constantes elásticas, el módulo de volumen, el factor de anisotropia, el indice de Poisson y el índice de Pugh.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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          year: 2024
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