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Strong Electronic Couplings between Ferrocenyl Centers Mediated by Bis-Ethynyl/Butadiynyl Diruthenium Bridges.

A series of trans-(FcC)RU(Y-DMBA)(CFc) with n, m = 1 and 2 and Y-DMBA as N,N'-dimethylbenzamidinate or N,N'-dimethyl-(3-methoxy)benzamidinate have been synthesized and characterized. The intramolecular Fc…Fc distances, established through single-crystal X-ray diffraction studies, range from 11.6 to...

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Published in:Journal of the American Chemical Society Vol. 127; no. 38; pp. 13354 - 13364
Main Authors: Guo-Lin Xu, Crutchley, Robert J., DeRosa, Maria C., Qing-Jiang Pan, Hong-Xing Zhang, Xiaoping Wang, Ren, Tong
Format: Article
Published: American Chemical Society 9/28/2005
Subjects:
Transition metals
Absorption
Ethanes
Optical diffraction
Optics
Molecules
Online Access:View this record in EBSCOhost